{"product_id":"9783540669432","title":"Metal-Oxo and Metal-Peroxo Species in Catalytic Oxidations (Structure and Bonding .97) (2000. X, 323 S. 89 SW-Abb. 235 mm)","description":"\u003cp\u003e§06§ §16§The present volume is a description of the current knowledge on the different metal-oxo and metal-peroxo species which are involved in catalytic oxidations. These highly reactivity metal-oxygen species are the key intermediates in heme or non-heme oxygenases, as well as in metal-catalyzed oxidations. The accumulated knowledge on these reactive entities will facilitate a better understanding of the different intermediates involved in the catalytic cycles of enzymes like cytochromes P-450, non-heme oxygenases, copper oxygenases, in the oxidation of water by the manganese-center of Photosystem II, in the chemistry of dioxiranes and also in DNA cleavage performed by activated bleomycin. The description of these metal-oxo and metal-peroxo species is based on physico-chemical data, reactivity results and also on theoretical calculations. §04§Active Iron-Oxo and Iron-Peroxo Species in Cytochromes P450 and Peroxidases; Oxo-Hydroxo Tautomerism with Water-Soluble Metalloporphyrins.- Nucleophilicity of Iron-Peroxo Porphyrin Complexes.- Characterization of High-Valent Oxo-Metalloporphyrins.- Characterization, Orbital Description, and Reactivity Patterns of Transition-Metal Oxo Species in the Gas Phase.- Quantum Chemical Studies on Metal-Oxo Species Related to the Mechanisms of Methane Monooxygenase and Photosynthetic Oxygen Evolution.- Characterization and Properties of Non-Heme Iron Peroxo Complexes.- Copper-Dioxygen and Copper-Oxo Species Relevant to Copper Oxygenases and Oxidases.- Rhenium-Oxo and Rhenium-Peroxo Complexes in Catalytic Oxidations.- Structure, Reactivity, and Selectivity of Metal-Peroxo Complexes Versus Dioxiranes.- Nature of Activated Bleomycin. §04§ller, O. Weichhold: Structure, Reactivity and Selectivity of Metal-Peroxo Complexes Versus Dioxiranes .- R.M. Burger: Nature of Activated Bleomycin\u003c\/p\u003e","brand":"SPRINGER, BERLIN","offers":[{"title":"Default Title","offer_id":52355481829687,"sku":"00000_00000_00000_00000","price":1191.9,"currency_code":"MYR","in_stock":true}],"thumbnail_url":"\/\/cdn.shopify.com\/s\/files\/1\/0962\/3548\/7543\/files\/9783540669432-1.jpg?v=1783270204","url":"https:\/\/kinokuniya.com.my\/products\/9783540669432","provider":"Books Kinokuniya Malaysia","version":"1.0","type":"link"}